You gotta give Leighton Meester credit, the "Gossip Girl" star has got us talking, about fashion that is. Sometimes she dazzles, sometimes she perplexes. But love her or not, no one can accuse Leighton (or Blair Waldorf for that matter) of playing it safe.

This daring black number was spot-on the recent MTV Movie Awards. By no means your average LBD, this look was venue-appropriate.